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Structure and preparation method of gadolinium oxide Gd2O3 powder

2021-11-01 09:48:06  News

Gadolinium oxide Gd2O3 powder overview

Gadolinium Oxide , the chemical formula is Gd2O3, using monazite or mixed rare earth ore as the raw material, after extraction and other purification steps, the samarium-gadolinium mixed rare earth solution is prepared, and the gadolinium oxalate is precipitated with oxalic acid. After separation, drying, and burning, Prepared gadolinium oxide. Preparation method: after extraction and other purification steps, a samarium-gadolinium mixed rare earth solution is prepared. Gadolinium oxalate is precipitated with oxalic acid, separated, dried, and burned to obtain gadolinium oxide.

Structure and preparation method of gadolinium oxide Gd2O3 powder

The oxide of Gadolinium Oxide Gd2O3 powder has two structures. The cubic (CI80, IA3, No.206) structure is similar to manganese (III) oxide and heavy trivalent lanthanide sesquioxide. There are two types of sites in the cubic structure. The coordination number of each site is 6, but the coordination geometry is different. The second form is monoclinic (Pearson symbol MS30, space group C2/M, number 12). At room temperature, the cubic structure is more stable. This phase becomes monoclinic at 1200°C. The melting point is higher than 2100℃~2420℃, mainly hexagonal phase.

Gadolinium oxide Gd2O3 powder can be formed by the thermal decomposition of hydroxide, nitrate, carbonate or oxalate. Oxidation d is formed on the surface of metal g.

Gadolinium oxide Gd2O3 powder is a strong alkaline oxide that can react with carbon dioxide to form carbonate. Easily soluble in common inorganic acids. Complications are that oxalic acid, fluoride, sulfate, and phosphate are extremely difficult to dissolve in water, and may cover oxide particles, preventing them from dissolving completely. At present, there are many methods for synthesizing oxide nanoparticles, mainly by reacting ionic ions with hydroxide to precipitate hydroxide, and then performing thermal dehydration to obtain oxide g. Nanoparticles are always coated with protective materials to prevent the formation of larger polycrystalline aggregates.

Ga nano-particle gadolinium oxide Gd2O3 powder is a potential MRI contrast agent. At 7.05 T (compared to 0.5-3 T of clinical MRI scanner, abnormally high electric field), prepare 20-40 nm oxide g particles to coat deshosides, and the relaxation time of each particle is 4.8 s-1 mm-1, ion Smaller particles between 2 and 7 nm are tested as MRI reagents.

Preparation method of gadolinium oxide Gd2O3 powder

It is obtained from the rare earth chloride solution after extraction, back extraction, zinc powder reduction, precipitation with oxalic acid, separation, and burning.

Gd(C2O4)3→Gd2O3+3CO2↑+3CO↑

Gadolinium oxide Gd2O3 powder is an inorganic compound with the molecular formula Gd2O3. It is one of the most common forms of rare earth element g, and its derivatives are potential magnetic resonance imaging contrast agents.

Application of Gadolinium Oxide Gd2O3 Powder

Used as yttrium aluminum and yttrium iron garnet dopants, sensitizing fluorescent materials in medical equipment, nuclear reactor control materials, raw materials for preparing metal gadolinium, magnetic bubble materials and optical prism additives, etc.

Color picture tube phosphor

Optical glass

Atomic reaction absorption material

The microwave application to be used is the preparation of gadolinium garnet yttrium.

Gadolinium oxide Gd2O3 powder price

The price of gadolinium oxide Gd2O3 powder will vary randomly with the production cost, transportation cost, international situation, exchange rate and market demand for Gd2O3 powder. Tanki New Materials Co., Ltd. aims to help various industries and chemical wholesalers find high-quality, low-cost nanomaterials and chemicals by providing a full set of customized services. If you are looking for gadolinium oxide Gd2O3 powder, please feel free to send it to get the latest price of gadolinium oxide Gd2O3 powder.

Gadolinium Oxide Gd2O3 Powder Supplier

As a global supplier of gadolinium oxide Gd2O3 powder, Tanki New Materials Co., Ltd. has extensive experience in the performance, application and cost-effective manufacturing of advanced technology and engineering materials. The company has successfully developed a series of powder materials (including oxides, carbides, nitrides, single metals, etc.), high-purity targets, functional ceramics, structural devices, and provides OEM services.

Technical Parameter of Gadolinium Oxide Gd2O3 Powder
ITEMSPECIFICATIONSTEST RESULTS
Gd2O3/TREO(%,Min)99.99999.999
TREO(%,Min)9999.64
RE Impurities(ppm/TREO,Max)
La2O3
<1.0
CeO2
<1.0
Pr6O11
<1.0
Nd2O3
<1.0
Sm2O3
<1.0
Eu2O3
<1.0
Tb4O7
1.5
Dy2O3
<1.0
Ho2O3
<1.0
Er2O3
<1.0
Tm2O3
<1.0
Yb2O3
<1.0
Lu2O3
<1.0
Y2O3
<1.0
Non-Re Impurities(ppm,Max)
Fe2O3
<1.0
CaO
4
SiO2
13
Cl-
<50
Al2O3
<50

L.O.I (%)
0.26


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